The role and necessity of the Hall effect experiment


Release Time:

Oct 27,2013

The role and necessity of the Hall cell experiment
The importance of the Hall cell experiment
The Hall cell experiment can quickly eliminate quality faults and is a necessary basis for rapid process adjustments. The Hall cell test piece is like an X-ray taken for a patient in a hospital. By interpreting the Hall cell test piece, many pieces of information about the plating solution can be obtained, thus allowing for a comprehensive understanding of the performance of the plating solution, avoiding quality accidents, facilitating process adjustments, and reducing detours.

 

Structure of the Hall cell:
Application characteristics of the Hall cell:
1. Reproducibility of plating solution performance, facilitating quick fault elimination

    When the composition of the plating solution deviates from the process range, or when there are impurities or imbalances in additives, there will be some characteristic reactions on the cathode test piece, such as streaks, pitting, blackening, burning in high areas, under-plating in low areas, and improper brightness range. Moreover, for a specific plating solution, the same cause always leads to the same result. This means that the Hall cell experiment has good reproducibility, allowing for the creation of a series of standard known good and faulty test pieces as references for quick troubleshooting of faulty plating solutions.
2. Basis for process adjustments, saving time and effort and reducing detours
When making tentative adjustments to the performance or composition of the electroplating solution, to avoid quality faults caused by improper adjustments, testing can first be conducted using the Hall cell. Multiple adjustment plans can be tested with a smaller amount of plating solution, and once successful, experiments can be conducted on the production line, increasing the success rate and avoiding unnecessary detours.
3. A practical tool for electroplating workers
Testing the plating solution through the Hall cell allows for determining the general range of the plating solution components without laboratory equipment, by displaying voltage and the appearance of the coating. It is an indispensable practical tool for electroplating workers, similar to a multimeter used by electricians.

 

Hall cell experiment instructions
Application range: Testing the comprehensive performance of electroplating solutions, checking whether the components of additives are balanced,

Troubleshooting of electroplating solutions;

Technical instructions:
Different currents and time descriptions used for different plating solutions are shown in the table below:

Plating type

Current (A)

Temperature (℃) Time Remarks
Copper plating 4 40 3-10 The lower limit for appearance experiments, the upper limit for additive consumption experiments.
Nickel plating 1 4 4  
Chrome plating 8-12 50-65 5-6 The temperature is the actual electroplating process temperature.

Current density distribution on the test piece: Ik=I(C1-C2lgL),
C1, C2—constants, in 250mL test solution, C1=5.1, C2=5.24;

Current Distance to the high current area of the test piece (cm)
0.10 0.50 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00
1 11.05 7.18 5.45 3.74 2.78 2.08 1.54 1.09 0.72 0.40 0.11
2 22.10 14.36 10.90 7.48 5.56 4.16 3.08 2.18 1.44 0.80 0.22
3 33.15 21.54 16.35 11.22 8.34 6.24 4.62 3.27 2.16 1.20 0.33
4 44.20 28.72 21.80 14.96 11.12 8.32 6.16 4.36 2.88 1.60 0.44
5 55.25 35.90 27.25 18.70 13.90 10.40 7.70 5.45 3.60 2.00 0.55
6 66.30 43.08 32.70 22.44 16.68 12.48 9.24 6.54 4.32 2.40 0.66
7 77.35 50.26 38.15 26.18 19.46 14.56 10.78 7.63 5.04 2.80 0.77
8 88.40 57.44 43.60 29.92 22.24 16.64 12.32 8.72 5.76 3.20 0.88
9 99.45 64.62 49.05 33.66 25.02 18.72 13.86 9.81 6.48 3.60 0.99
10 110.50 71.80 54.50 37.40 27.80 20.80 15.40 10.90 7.20 4.00 1.10
11 121.55 78.98 59.95 41.14 30.58 22.88 16.94 11.99 7.92 4.40 1.21
12 132.60 86.16 65.40 44.88 33.36 24.96 18.48 13.08 8.64 4.80 1.32

 

Description of the standard test piece appearance:

Classification Standard test piece appearance
Nickel plating The coating is matte, with burnt edges in the high area, good flatness in the mid-high area, and slight black appearance coating on the edges of the low area.
Copper plating The high area has no scorching or slight scorching (within a range of 1mm), the mid-high area is bright, with a brightness range of 50-70% being appropriate, and there are no nodules or pores observed under magnification on the surface. The low area has a matte coating, and the surface is leveled.
Chrome plating The high area has a slight gray-white coating (scorched), within a range of 2mm, the mid-high area is bright and leveled, with a brightness range of over 50%, and the low area has a gray-white coating, with the edge of the low area having a coating leakage range of less than 10mm.

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